Here are the postulates of Dalton’s atomic theory. First published in 1807, many of Dalton’s hypotheses about the microscopic features of matter are still valid in modern atomic theory. The Aristotelian view of the composition of matter held sway for over two thousand years, until English schoolteacher John Dalton helped to revolutionize chemistry with his hypothesis that the behavior of matter could be explained using an atomic theory. Interestingly, these philosophers thought about atoms and “elements” as philosophical concepts, but apparently never considered performing experiments to test their ideas. Later, Aristotle and others came to the conclusion that matter consisted of various combinations of the four “elements”-fire, earth, air, and water-and could be infinitely divided. In the fifth century BC, Leucippus and Democritus argued that all matter was composed of small, finite particles that they called atomos, a term derived from the Greek word for “indivisible.” They thought of atoms as moving particles that differed in shape and size, and which could join together. The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers, the scientists of their day. State the postulates of Dalton’s atomic theory.Appendix L: Standard Electrode (Half-Cell) Potentialsīy the end of this section, you will be able to:.Appendix K: Formation Constants for Complex Ions.Appendix I: Ionization Constants of Weak Bases.Appendix H: Ionization Constants of Weak Acids.Appendix G: Standard Thermodynamic Properties for Selected Substances. Appendix F: Composition of Commercial Acids and Bases.Appendix D: Fundamental Physical Constants.Appendix C: Units and Conversion Factors.Second Law of Thermodynamics and Gibbs Free Energy.Application: Precipitation and Dissolution.Shifting Equilibria: LeChatelier’s Principle.Chemical Equilibria and Applications Toggle Dropdown Collision Theory and Factors Affecting Reaction Rates.Solutions and Colligative Properties Toggle Dropdown Liquids, Solids, and Modern Materials Toggle Dropdown Chemical Bonding and Molecular Geometry Toggle Dropdown Thermochemical Guidelines, Enthalpy of Formation and Hess's Law.Solution Stoichiometry and Combustion Analysis.Writing and Balancing Chemical Equations.Stoichiometry of Chemical Reactions Toggle Dropdown Determining Empirical and Molecular Formulas.Composition of Substances and Solutions Toggle Dropdown Molecular and Ionic Compounds and Their Nomenclature.Early Ideas and Evolution of Atomic Theory.Measurements and Uncertainty in Measurement.Classification, Physical and Chemical Properties.
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Her rescue, says Sergeant Zaglifa, was an unexpected reward for what he calls the "physically and emotionally draining" work of capturing child predators. Working with other agents, he traced Mancuso's Internet address to a location near Pittsburgh, where he was later arrested.ĭuring their investigation, police officials had no way of knowing that the little girl in the photographs was Mancuso's adopted daughter. Sergeant Zaglifa says his instinct told him this man was an absolute danger to children. Posing as a pedophile, Chicago area police officer Mike Zaglifa discovered Mancuso in an online chat room. Back in the states, Masha expected a nice American home with a bedroom all her own. No phone calls were made to his ex-wife or to his biological daughter. What she didn't know was the adoption agency failed to properly check her new father's background. But nothing could have been farther from the truth. Mancuso seemed like her knight in shining armor. He visited Masha several times at the orphanage, took her to nice dinners, and bought her candy. After months of waiting, Mancuso traveled to Russia to meet his new daughter. He contacted a New Jersey adoption agency requesting information on 5-year-old Caucasian girls, and chose Masha from a videotape. Meanwhile, 41-year-old Matthew Mancuso, a divorced father in Pennsylvania, was looking for a little girl to adopt. Soon after recovering from her traumatic ordeal, Masha was sent to an orphanage where she prayed that a good family would come to rescue her. Her own mother tried to kill her when she was only 4 years old by stabbing her in the back of the neck with a kitchen knife. She was born in southern Russia to an alcoholic mother and a father she never knew. But they have been rapidly replaced by a growing number of these so-called model sites, Internet locations that offer scores of original photographs of scantily clad under-age children like Sparkle, often posed in ways requested by subscribers.At 13 years old, Masha has already survived the unthinkable. In recent months, an array of investigations of the child pornography business - by the Justice Department, state and local law enforcement and Congress - have contributed to wholesale shutdowns of some of the most sexually explicit Internet sites trafficking in child images. Sparkle is one of hundreds of children being photographed by adults, part of what appears to be the latest trend in online child exploitation: Web sites for pedophiles offering explicit, sexualized images of children who are covered by bits of clothing - all in the questionable hope of allowing producers, distributors and customers to avoid child pornography charges. According to the posted schedule, new photographs of her - many clearly intended to be erotic, all supposedly taken that week - are posted online every Friday for her growing legions of admirers. She has thousands of fans from around the world, membership lists show, who pay as much as $30 a month to see images of her. In just over seven months, the model has become an online phenomenon. She gazes at the viewer, her face showing a wisp of a smile that seems to have been coaxed from off-camera. Her tight panties and skimpy top are soaked and revealing. In the photograph, the model is shown rising out of a bubble bath, suds dripping from her body. Often, such a service opens up the design possibilities of your project and prevents you from repeatedly using the same fonts in your projects.Ī few places to find inspiration, photography, textures, colors, and more: Instead of licensing individual fonts, you can sign up for the plan that best suits your needs and get a library of fonts from which to choose. Typekit is a subscription service for fonts which you can sync to your computer or use on a website. Kuler is a Mauritian Creole word for color. After downloading Switchboard from Adobe Labs, users using the desktop version of Color can export a color scheme straight into Adobe Photoshop, Adobe Illustrator, and Adobe InDesign. It is available in browser-hosted variants as well as in desktop versions using the Adobe AIR runtime. Tools & Resources to Help Create Mood BoardĪdobe Color, formerly known as Adobe Kuler, is an internet application from Adobe Systems that lets individuals try out, create, and save various color schemes, each of which consists of a set of five colors. They can also be used for more broad purposes such as using an image to convey a certain tone which you want to infuse throughout your project. These can be highly specific such as using a given photo to recreate a texture. It is also recommended to include a number of images or photos with your mood board. Similarly, a color palet specific to your project will keep new designs coherent with one another. By having a set of defined typographic fonts, you will simplify the following development stages and provide a needed consistency across designs. Some of these elements are the most practical: typography and colors. While you can add any design inspiration to your mood board, there are some common elements which will surely help within the scope of your web design project. Standard Mood Board Elements for Web Design This will help keep an assignment on track and prevent a mashing of incongruous styles. If during the buildout stages new elements are proposed, then you can always reference your initial design inspirations to see if these proposed changes are inline with the original direction. You can continue to consult the board throughout the development process. Mood boards, however, aren't strictly limited to the initial planning stages of a project. By laying out a project's specific design inspiration, you can better find repeating patterns, styles, and elements which will ultimately produce a cohesive design. Mood boards help ground the style and design direction of a project. With a blank canvas, anything is possible. Often, the initial stages of a web design project can be a bit open in terms of direction. There’s no right or wrong way to create one as long it inspires you. You can get inspiration from anything and anywhere. You can create one in a digital format using screen captures or you can have a physical board where elements are pieced together from various mediums: magazine tear outs, photography, books, a piece of fabric or texture, etc. There are several different ways to create mood boards. Gathering different elements, typography, color, textures and photography styles are essential for setting the tone on your design. It lets you know what the “look,” “feel,” and “tone” of project will be. A mood board is a visual collage of inspiration to help facilitate the beginning stages of a creative project. Step-daughter, Serita Bolden special nieces, Annie DorisĬollins, Joan Marie Jackson devoted brother-in-law, Lenzy Brown best friend, Karetha Fowler special friend, Miriam Fling the Bibleway Church family and a host of family and friends. Memories: a loving granddaughter, Dallas Sparks Washington and Lena (Jackson) Williams husband, Herbert Brown daughter, Holland Faye Brown-Sparks sisters, Ola Mae Newton, Georgia Williams, Eunice Dudley, Brunice Williams, Stella Mae Williams, Annie L Hobbs brothers, Jerry Williams, James D Collins, and Arthur Collins. Hattie Brown was predeceased by her parents, George Michael Berrys passing at the age of 61 has been publicly announced by Unity Funeral Home. When asked why she shopped so much, she replied, “Because I can” and, “You never know when you won’t be able too.” Funeral services provided by: Unity Funeral Home. She enjoyed socializing with friends and family and loved shopping. She was an avid reader and strong proponent of higher education. Hattie had a zest for living and a passion for traveling. Mother Brown enjoyed setting the example for others to follow and being a “difference maker.” Her service in this capacity enabled her to touch the lives of many – as a role model, mentor, and teacher. She enjoyed preparing for and teaching Sunday School and was revered as a Church Mother. Ronald Millss passing has been publicly announced by Unity Funeral Home in Dothan, AL.Legacy invites you to offer condolences and share memories of Ronald in the Guest Book below. Her efforts to seek the kingdom of God and His righteousness led her to the Bibleway Church in Dothan, Alabama where under the leadership of Bishop Russell Gordon she was an exemplary member. Hattie gave her life to Christ at an early age and was a faithful servant of the Lord. She relocated to Buffalo, New York, after being united in marriage to Herbert Brown, where she taught in the Buffalo City School District until retiring to Dothan, Alabama. Everyone has felt his love through jokes,laughter,and his ability to make the best of a bad situation. He departed this life June 2,2021 in Dothan, AL after a brief illness.Britts gift in this life was to give love freely. Hattie, affectionately known as “Eldora” or “Dora,” received her Bachelor’s degree in Education from Alabama State University and her Master’s Degree in Library Science from the State Dewayne Britt McNealy was born Decemin Headland, Al to Ms.Dorothy McNealy and Mr. Quietly, on Thursday, in Dothan, Alabama, she entered into eternal rest. Hattie L Dora Williams Brown was born in Houston County, Alabama on Decemto the late George Washington and Lena (Jackson) Williams. of Gordon, AL., 41– grandchildren, 29 - great grandchildren, a host of relatives and friends.Mrs. Davin (Jessica) Wesley of Dothan, AL., five daughters: Laura (Jerrmiah) Salter of Webb, AL., Sabrina (Willie) Knight of Gordon, AL., Roshonda (Jemmie) Watford of Stone Mountain, GA., Vanessa (Joseph) Percival, Virginia Buggs all of Decatur, GA., one sister: Julia Johnson, one brother: Hezekiah Thomas Jr., three sister-in- laws: Marene, Evelyn, and Helen Smith od Donalsonville, GA., one nephew: Augusta Grimsley Jr. John ( Arylica) Wesley Jr., of Webb, Al., Ira (Shawanna) Wesley of Ashford, AL., Terrance (Kimberly) Wesley of Cowarts, AL., Rickey Wesley, Fredrick Wesley, Mickey Wesley, Reginald Wesley all of Gordon, AL. He leaves to cherish his memories, eight sons: Rev. He was preceded in death by his parents Annie Lee Wesley and Hezekiah Thomas his wife of 47 years, Annie Lee Wesley, one daughter: Lawanda Wesley, one great grand daughter: Purpose Annie Lee Nash, two brothers: Jessie Gosha, Augusta Grimsley Sr. Later in life he accepted Christ as his personal Savior. farmed for over 40 years with Jeffcoat Farms until his early retirement. On October 21, 2022, at his home, he went peacefully to be with the Lord. to the late Annie Lee Wesley and Hezekiah Thomas. If you put this on your house, it's definitely beginning to look a lot like Christmas. It's super bright, super colorful, and super fun. With 12 Christmas patterns, five snowflake patterns, and even some gypsophila patterns, there's a feast for the eyes to be had here and a great choice of outdoor Christmas projector lights. Shop for Christmas Light Projectors in Christmas Lights. All these can be controlled remotely, with timer settings and presets, so you're not burning electricity when you don't want to be. Leaping reindeer, singing snowmen, waving Father Christmases-the whole nine yards. The Christmas slide patterns on offer here are a grotto full of bright, cheerful, wonderous Christmas scenes that will capture kids' imaginations. There's a 16.4-foot power cord to run back to your power outlet, and their IP65 waterproof design means the winter weather won't trouble them-not even when it's cold outside. This double-head Christmas projector light has 16 different festive projections, with high-brightness LEDs built-in to cast them over distances of up to 32 feet. But if you’re after something more subtle that looks beautiful and perfectly complements the season, this snowfall projector can provide you with that white Christmas you’ve been dreaming of. If you’re looking for Santas, snowmen, and reindeer to dance across the house this Christmas, this outdoor projector probably isn’t for you. And its 9.8-foot power cord should provide plenty of length to reach a suitable outlet. It’s also IP65 waterproof, with an operational temperature range of minus 25 to 40 degrees Fahrenheit, so it can power through even when the winter weather itself isn’t quite so romantic. This projector has a 90-120-degree rotation range, and the projection angle can be altered to suit taller or shorter homes. Christmas Projector Lights with Remote, 2 in 1 Xmas Projector Light Christmas Theme Outdoor Indoor, Waterproof HD Projector Lamp 360☊utomatic Rotation for Xmas,Party,Garden Home Decorative Lighting. And thanks to its double-head projection, it can cover a much larger area than other outdoor projectors. This double-head snowfall and snowflake projector from Anerbili will transform the outside of your home into a veritable winter wonderland. 10 coupon applied at checkout Save 10 with coupon. If any issue arise, we will happily send a replacement on us, satisfaction is our number one priority at 1byone.If you’re looking for a magical snowfall to cascade over your house this Christmas, then look no further. Laser Christmas Projector Lights Outdoor, 3 Color Laser Light Projector, Firefly Lights Show with RF Remote, Waterproof, Indoor Holiday Decoration, Christmas Gift, Wedding, Home Decor, Party, Garden. This projector light comes with 24-month guarantee. Here at 1byone, we standby our products 100%. Range of Application: Project the patterns onto wall, building, dance floor or any flat surface. When powering off the projector light using the power on/off buttons, the projector light will remember the last projecting patterns, no need to set up again. The LED Projector Light is very easy to install, just plug the stake in the ground or lawn or use the stand to have it stand on its own, no ladders or other tools needed. Light along with moving patterns create a unique display on your home, the effect will be great. Power on and get maximum brightness right away, no need to wait for the projector to warm up. No need to carefully avoid direct eye contact with the light anymore, the gentle soft LED light instead of laser light, better to protect eyes as night light especially for baby kids and enjoy your day. A perfect choice for your Christmas decoration. With 8 built-in exclusively designed dynamic Christmas patterns, you can choose to cycle all patterns for 10 seconds or cycle fixed pattern. 1byone Christmas Decorations Light Projector, Auto-Shifting Images and Auto-Switchable Pattern, Outdoor/Indoor Use, IP65 Water-Resistant, Eight in One A positive number indicates that you’re in the black and, therefore, making money. When you add up all of your income then subtract your total expenses, you should have a positive or negative number. A P&L statement is a high-level overview that shows whether your organization is profitable or in the red. Now you can better understand your business finances by creating a profit and loss (P&L) statement. You’ve accounted for your income and fixed, variable, and emergency expenses. You can’t predict when you’ll need to pay for an emergency expense or how much it might cost, but you can set aside a cash reserve to lessen the burden. New equipment, hiring expenses, and unplanned events can add up, so it’s wise to plan ahead as much as you can. As a business owner, you’re likely familiar with unexpected expenses. Life is full of unexpected circumstances. Prepare for emergency and one-time expenses Billable staff wages (freelancers, outsourced work, etc.)Īfter identifying your variable expenses and estimating how much they cost each month, subtract the amount from your income.Ĥ.These variable expenses may be harder to predict, but you can refer to old receipts and invoices to estimate them. In addition to your fixed costs, you might anticipate monthly operating expenses that may not always be the same amount. Once you’ve tallied up your fixed expenses, you can subtract that number from the total income you calculated in step 1. The one-off expenses, or variable costs? Not so much-more on that in a minute. These costs are easy to predict, so they’re easy to work into your budget. Whether you pay bills monthly, weekly, or annually, you can expect to spend a set amount of dollars on each expense. Fixed costs are expenses that remain consistent throughout the year. Once you’ve added all of your business’s income together, you can subtract your fixed costs. Depending on your business model, you may have several income sources, so be sure to include any and all revenue streams in this section. To find out how much money your business is bringing in, refer to your profit and loss statements. It also indicates your take-home pay and whether your business performance is growing or stagnating. Your net income determines how much you can afford to spend. Whether you’re optimizing your personal spending or building a business budget, your first step should be aggregating all of your forms of income. Let’s now take a look at the steps you need to take to create one. Now you know what a business budget is, why it’s important, and the essential components. She teaches English and writing full time at Northern Virginia Community College, a job she also held for her eight years as second lady when her husband was vice president.įrom her perch at the White House, she has spent time advocating for education issues, helping military families through her "Joining Forces" initiative and working to end cancer through the "Cancer Moonshot." The first lady is one of the Biden administration's most often used surrogates at events across the country. The first lady told CNN she is "all for" her husband running for reelection in 2024 but also left an opening should he decide not to run, noting, "If he wants to do something else, we're there too."īiden plays a unique role as first lady, the first to hold a full-time paid job outside of the White House. RELATED: First lady Jill Biden in Africa to show administration's commitment, White House saysīiden, who has been married to the president for nearly 46 years, has long said she's not an adviser to her husband, but she is his most trusted partner and wields a significant amount of influence within the White House. Her comments came during a wide-ranging interview with CNN on her five-day visit to Africa, which included stops in Namibia and Kenya. He understands both sides, which is part of his strength." "I'm always better like, 'This person feels this way.' 'Yes, but this is why they,' - you know, he's very good at that - understanding why people feel the way they do. "Well, sometimes I don't, I may not see things from his perspective. "I think it's a good balance really."Īnd on the other side of the relationship, Biden said her husband helps her understand there are different ways of looking at issues and viewpoints. I'm out, you know, somewhere in the United States," she added. "It's in that context because I'm out every day. It's like, let me tell you what I saw or what I heard, or what people are saying to me." "Certainly I tell him stories, and I have things that I've seen and things that people want and where their challenges are," she said during an interview in Nairobi, Kenya, which will air as part of a forthcoming special event, "CNN Primetime: Jill Biden Abroad." "So, it's not that I'm like weighing in. 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After the player defeats Nolok in Fort Magma, the final track of STK, Tux rescues Gnu from his prison. Nolok then visits Tux and tells him that he has kidnapped Gnu unless Tux and his friends can defeat Nolok, the 'King of the Karts', Gnu would become his supper. Story mode is used to unlock tracks and characters for single and multi-player modes.Īt the beginning of story mode, Gnu, the leader of the free/libre and open-source world, is captured by Nolok, the villain in STK, with his spaceship. Unlike Mario Kart, STK has a story associated with gameplay, similar to Crash Team Racing. The mascots for many other projects are available as add-ons from SuperTuxKart's add-ons website. The character Nolok does not represent a particular open source project, but was created by the SuperTux project as the antagonist of Tux. The official playable characters of SuperTuxKart are the mascots of free and open-source projects. Networking modes were introduced in version 1.0. The game supports single player, local multiplayer, WAN multiplayer, and LAN multiplayer modes. For example, Mozilla Thunderbird plays the referee, flagging the start of the race and saving players when they drive off the course. The game features the mascots of several open source projects. SuperTuxKart 's gameplay is similar to that of the Mario Kart series, but also has distinct elements, such as collecting and using cans of Nitro. Gameplay GNU and Nolok in the beginning story of Story Mode in STK Split-screen 4-player multiplayer in SuperTuxKart (2017, 0.9.3) SuperTuxKart is under active development by the game's community. When TuxKart's development ended around March 2004, a fork as SuperTuxKart was conducted by other developers in 2006. SuperTuxKart started as a fork of TuxKart, originally developed by Steve and Oliver Baker in 2000. SuperTuxKart is cross-platform, running on Linux, macOS, Windows, iOS (beta), Android systems and Nintendo Switch ( homebrew). It features mascots of various open-source projects. SuperTuxKart ( STK) is a free and open-source kart racing game, distributed under the terms of the GNU General Public License, version 3. GPL, CC BY-SA or more permissive (assets) *The Level Editor does not currently support boss fights, teleporters in world maps, or scrolling text scenes for intros/outros of worlds.Linux, macOS, Microsoft Windows, Android, iOS (in beta), Nintendo Switch Many bug fixes and optimisations (and probably new bugs to fix, given the complexity of the new features □).A huge restructuring of the game's internals to make way for the level editor.A toggle for auto-run (you can now choose to walk).The editor is also completely usable on mobile devices, with relevant adjustments being made to support touch controls. If you would like to give feedback or suggestions on its design for future improvement, please join the SuperTux Classic Discord server. The editor was designed to be as intuitive as possible to use. This editor is fully featured and supports all features within the game, with a few exceptions*. You can now make your own SuperTux Classic levels straight from within the game itself! An all-new, custom-built level editor has been added into SuperTux Classic! |
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